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Direct Recovery of Spilled Oil using Hierarchically Porous Oil Scoop with Capillary-Induced Anti-Oil-Fouling
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2020-11-18 , DOI: 10.1016/j.jhazmat.2020.124549
Tae-Jun Ko , Seohyun Cho , Seong Jin Kim , Young A Lee , Do Hyun Kim , Wonjin Jo , Ho-Young Kim , Shu Yang , Kyu Hwan Oh , Myoung-Woon Moon

The pitcher plant has evolved its hierarchically grooved peristome to enhance a water-based slippery system for capturing insects with oil-covered footpads. Based on this, we proposed a hierarchically porous oil scoop (HPOS) with capillary-induced oil peel-off ability for repeatable spilled oil recovery. As HPOS scoops oil-water mixture, water passes through the hole while the oil is confined within a curved geometry. The filter in HPOS has three levels of porous structures; (1) 3D-printed mesh structure with sub-millimeter scale hole to filter out oil from an oil-water mixture, (2) internal micropore in fibers enhancing capillarity and water transport, (3) O2 plasma-induced high-aspect-ratio nanopillar structures imposing anti-oil-fouling property with capillary-induced oil peeling. As the oil-contaminated HPOS contacts water, water meniscus rises and peels-off the oil immediately at the air-water interface. The oil-peel-off ability of HPOS would prevent pores from clogging by oils for reuse. The study demonstrated that the HPOS scoops highly viscous oil (up to 5,000 mm²·s⁻¹ of viscosity) with a high recovery rate (> 95%), leaving the filtered water with low oil content (< 10 ppm), which satisfies the discharge criterion of 15 ppm.



中文翻译:

使用分层多孔油勺和毛细管诱导的防油垢技术直接回收溢油

水罐厂已经改良了它的分层有沟纹的Peristome,以增强一种水基滑滑系统,该系统可以用油覆盖的脚垫捕获昆虫。基于此,我们提出了一种具有毛细孔引起的油剥落能力的分层多孔油勺(HPOS),以进行可重复的溢油回收。当HPOS收集油水混合物时,水会通过孔,而油则被限制在弯曲的几何形状内。HPOS中的过滤器具有三个级别的多孔结构。(1)3D打印的网状结构,具有亚毫米刻度孔,可从油水混合物中滤出油;(2)纤维中的内部微孔可增强毛细作用和水的输送;(3)O 2等离子体诱导的高纵横比纳米柱结构,具有毛细管诱导的油剥落,具有抗油污特性。当受油污染的HPOS与水接触时,水弯液面上升并立即在空气-水界面处剥离油。HPOS的油剥落能力可防止油被毛孔阻塞而重新使用。研究表明,HPOS可以以高回收率(> 95%)收集高粘度油(粘度高达5,000mm²·s⁻1),而滤出的水却具有低油含量(<10 ppm),可以满足放电标准为15 ppm。

更新日期:2020-11-18
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