Iodonium catalysis is described here to accomplish an intermolecular olefin oxyamination reaction. Urea is used as the O- and N-source to add across both activated and unactivated alkenes in a regioselective manner. Mechanistic studies confirm the presence of an iodonium intermediate.1 Introduction2 Hypothesis3 Optimizations and Scope4 Mechanistic Probes5 Future Outlook

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卤素催化：烯烃功能化中未充分利用和探索的催化概念

此处描述了碘催化以完成分子间烯烃胺化反应。尿素用作 O 源和 N 源，以区域选择性方式添加到活化和未活化的烯烃中。机理研究证实了碘鎓中间体的存在。1 介绍2 假设3 优化和范围4 机理探索5 未来展望