Innovative Protocols in the Catalytic Oxidation of 5‐Hydroxymethylfurfural,ChemSusChem

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Innovative Protocols in the Catalytic Oxidation of 5‐Hydroxymethylfurfural
ChemSusChem ( IF 7.5 ) Pub Date : 2020-11-17 , DOI: 10.1002/cssc.202002232
Ting Su ₁ , Deyang Zhao ₂ , Yantao Wang ₃ , Hongying Lü ₁ , Rajender S. Varma ₄ , Christophe Len _{5,

6}

Affiliation

5‐Hydroxymethylfurfural (HMF) has been identified as one of the most promising biomass‐based multi‐purpose platform molecules. Innovative protocols, namely electrocatalysis, photocatalysis, and microwave (MW)‐assisted chemistry, as well as continuous‐flow systems, add a new dimension and another promising toolbox for the oxidation of HMF in recent years. This Minireview deals with recent progress in the catalytic oxidation of HMF to 2,5‐furandicarboxylic acid (FDCA) and other intermediates using noble, non‐noble, and metal‐free systems deploying emerging protocols. Selective HMF downstream oxidation products could be obtained not only via common catalyst modifications, namely nature of the metal, preparative method, and the property of deployed support, but also by using innovative processes.

中文翻译：

5-羟基甲基糠醛催化氧化的创新方案

5-羟甲基糠醛（HMF）被认为是最有前途的基于生物质的多功能平台分子之一。近年来，电催化，光催化和微波（MW）辅助化学等创新方案以及连续流系统为HMF的氧化增加了新的领域和另一个有希望的工具箱。这份Minireview涉及使用新兴方案的贵金属，非贵金属和无金属系统将HMF催化氧化为2,5-呋喃二甲酸（FDCA）和其他中间体的最新进展。选择性HMF下游氧化产物不仅可以通过常见的催化剂改性（即金属的性质，制备方法和展开的载体的性质）来获得，而且可以通过使用创新的方法来获得。

更新日期：2021-01-08

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