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Visualization of the oxygen partial pressure in a proton exchange membrane fuel cell during cell operation with low oxygen concentrations
Journal of Power Sources ( IF 8.1 ) Pub Date : 2020-11-17 , DOI: 10.1016/j.jpowsour.2020.229193
Yu Kakizawa , Christopher L. Schreiber , Shogo Takamuku , Makoto Uchida , Akihiro Iiyama , Junji Inukai

The oxygen starvation was investigated in a single-serpentine proton exchange membrane fuel cell (PEMFC) at low oxygen concentrations of 3, 5, and 10% in air. At the voltage lower than 0.6 V, the cell performance abruptly decreased at all oxygen concentrations, but most significantly at 3%. To investigate the processes of the oxygen starvation, the oxygen partial pressure (p(O2)) on the gas diffusion layer (GDL) at low oxygen concentrations (Φ(O2)) of 3, 5, and 10% in air was visualized at the cathode in a running single-serpentine PEMFC by using an oxygen-sensitive dye coated on the GDL. p(O2) continuously lowered in the operating fuel cell along the gas flow channel. At Φ(O2) = 3 and 5% and at oxygen utilizations higher than 90%, p(O2) on the GDL became 0 kPa and susceptible to degradation. The evolution of hydrogen at the cathode was proposed, which might have chemically consumed oxygen near the outlet. Also in a stack, the influence of this hydrogen evolution prior to the hydrogen pumping must be considered.



中文翻译:

可视化在低氧浓度的电池运行过程中质子交换膜燃料电池中的氧分压

在单蛇形质子交换膜燃料电池(PEMFC)中,在空气中3、5和10%的低氧浓度下研究了缺氧情况。在低于0.6 V的电压下,在所有氧气浓度下,电池性能都会突然下降,但最显着的是3%。为了研究缺氧的过程,在空气中的低氧浓度(Φ(O 2))为3%,5%和10%的情况下,气体扩散层(GDL)上的氧分压(p(O 2))为通过使用涂在GDL上的对氧敏感的染料,可以在运行中的单蛇形PEMFC的阴极上看到图像。在运行的燃料电池中,p(O 2)沿着气流通道连续降低。在Φ(O 2)= 3和5%,在氧气利用率高于90%时,GDL上的p(O 2)变为0 kPa,易于降解。有人提出在阴极放出氢气,可能在出口附近化学消耗了氧气。同样在烟囱中,必须考虑在抽氢之前这种析氢的影响。

更新日期:2020-11-17
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