Abstract

The review addresses methods for the synthesis of metal complexes of crown-substituted porphyrins; structural features of these compounds; and the influence of metal cations on the luminescence and other photophysical properties of metal crown-porphyrin complexes. Thermochromic, fluorescence, and phosphorescence properties of metal crown-porphyrins are analyzed; the applicability of these compounds as luminescence-based temperature sensors, sensors for alkali metal cations, thermochromic materials, and active components of photovoltaic energy converters are considered.

中文翻译：

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金属冠卟啉配合物：制备，光学性质和应用（综述）

摘要

综述阐述了冠取代卟啉金属配合物的合成方法。这些化合物的结构特征；以及金属阳离子对金属冠-卟啉配合物的发光和其他光物理性质的影响。分析了金属冠状卟啉的热致变色，荧光和磷光性质；考虑了这些化合物作为基于发光的温度传感器，用于碱金属阳离子的传感器，热致变色材料以及光伏能量转换器的活性成分的适用性。