Abstract

The reaction of anilines containing a 1,2,4-oxadiazole moiety with the bis(xylylisocyanide) Pd(II) complex leads to the formation of acyclic diaminocarbene complexes. The oxadiazole ring is not involved in the reaction. Composition and structure of the obtained complexes have been confirmed by means of mass spectrometry, NMR spectroscopy, and single-crystal X-ray diffraction analysis.

中文翻译：

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含1,2,4-恶二唑部分的钯（II）无环二氨基卡宾配合物的合成与结构研究

摘要

含有1,2,4-恶二唑部分的苯胺与双（二甲苯基异氰化物）Pd（II）配合物的反应导致形成无环二氨基卡宾配合物。恶二唑环不参与反应。所获得的配合物的组成和结构已经通过质谱，NMR谱和单晶X射线衍射分析得以证实。