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Changes in Resistance and Bandgap of V 2 O 5 and Ge 2 Sb 2 Te 5 during Phase Transition
Journal of Electronic Materials ( IF 2.2 ) Pub Date : 2020-11-16 , DOI: 10.1007/s11664-020-08599-5
Yongkang Xu , Yifeng Hu , Song Sun , Tianshu Lai

V2O5 and Ge2Sb2Te5 (GST) films have been prepared by magnetron sputtering, and their transformation from amorphous to crystalline state studied by in situ resistance temperature measurements. During the heating process, a two-step transition was observed for both films, revealing three resistances corresponding to amorphous, intermediate, and crystalline states. The two phase-transition temperatures were 371.1°C and 394.0°C for V2O5, much higher than the values of ∼ 172.4°C and 240.4°C for GST. Compared with GST, the resistance of V2O5 was two orders of magnitude higher. The changes in the resistance and bandgap of V2O5 and GST during phase transition were investigated in detail. A phase-change memory device based on V2O5 was fabricated. Compared with GST, V2O5 exhibited a lower operating power and shorter phase-transition time. The application potential of V2O5 and GST for multilevel storage was compared.



中文翻译:

V 2 O 5和Ge 2 Sb 2 Te 5相变过程中电阻和带隙的变化

通过磁控溅射制备了V 2 O 5和Ge 2 Sb 2 Te 5(GST)薄膜,并通过原位电阻温度测量研究了它们从非晶态到结晶态的转变。在加热过程中,两个膜均观察到两步过渡,显示出对应于非晶态,中间态和结晶态的三个电阻。V 2 O 5的两个相变温度分别为371.1°C和394.0°C ,远高于GST的〜172.4°C和240.4°C。与GST相比,V 2 O 5的电阻高出两个数量级。详细研究了相变过程中V 2 O 5和GST的电阻和带隙的变化。制造了基于V 2 O 5的相变存储器件。与GST相比,V 2 O 5具有较低的工作功率和较短的相变时间。比较了V 2 O 5和GST在多层存储中的应用潜力。

更新日期:2020-11-17
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