Synthesis and derivatization of hetera-buckybowls,Organic & Biomolecular Chemistry

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Synthesis and derivatization of hetera-buckybowls
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020-10-30 , DOI: 10.1039/d0ob01931c
Wenbo Wang _{1,

2,

3,

4} , Xiangfeng Shao _{1,

2,

3,

4}

Affiliation

Buckybowls have concave and convex surfaces with distinct π-electron cloud distribution, and consequently they show unique structural and electronic features as compared to planar aromatic polycycles. Doping the π-framework of buckybowls with heteroatoms is an efficient scheme to tailor inherent properties, because the nature of heteroatoms plays a pivotal role in the structural and electronic characteristics of the resulting hetera-buckybowls. The design, synthesis, and derivatization of hetera-buckybowls open an avenue for obtaining fascinating organic entities not only of fundamental importance but also of promising applications in optoelectronics. In this review, we summarize the advances in hetera-buckybowl chemistry, particularly the synthetic strategies toward these scaffolds.

中文翻译：

杂巴鱼缸的合成与衍生

Buckybowls的凹凸表面具有明显的π电子云分布，因此与平面芳族多环化合物相比，它们具有独特的结构和电子特征。用杂原子掺杂Buckybowls的π骨架是一种有效的方案，可定制内在特性，因为杂原子的性质在所得杂合Buckybowls的结构和电子特性中起着关键作用。杂巴桶的设计，合成和衍生化为获取引人入胜的有机实体开辟了一条道路，这些有机实体不仅具有根本的重要性，而且还具有光电子学的广阔应用前景。在这篇综述中，我们总结了杂巴基化学的进展，特别是针对这些支架的合成策略。

更新日期：2020-11-16

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