Water, Air, & Soil Pollution ( IF 3.8 ) Pub Date : 2020-11-16 , DOI: 10.1007/s11270-020-04917-z Dominique Richard , Alfonso Mucci , Carmen M. Neculita , Gérald J. Zagury
Sorption is an effective process for the remediation of mine water with low metal concentrations. To identify promising low-cost organic sorbents for nickel (Ni), adsorption and retention properties of peat, compost, brown algae, sawdust, and wood ash were compared. Batch adsorption and desorption experiments were conducted at pH 7 in 0.05 M NaNO3 solutions to simulate the ionic strength and pH of a contaminated neutral drainage. Results of adsorption kinetic experiments were best represented by the Elovich model and the fastest rates were obtained with peat (796,075 mg g−1 min−1) and compost (791 mg g−1 min−1). Results of equilibration adsorption experiments were fitted to Langmuir and Freundlich isotherms and the highest adsorption capacities were observed for peat (around 22 mg g−1) and compost (around 9 mg g−1). Desorption experiments revealed that peat and compost adsorbed more Ni and also released a lower percentage of the adsorbed metal upon exposure to Ni-free solutions.
中文翻译:
被动处理被镍污染的合成中性矿山排水的有机材料比较:吸附和解吸动力学及等温线
吸附是修复低金属浓度矿井水的有效方法。为了确定有前途的低成本有机镍吸附剂,比较了泥炭,堆肥,褐藻,锯末和木灰的吸附和保留特性。在pH值为7的0.05 M NaNO 3溶液中进行分批吸附和解吸实验,以模拟受污染的中性排水的离子强度和pH。吸附动力学实验的结果最好用Elovich模型代表,用泥炭(796,075 mg g -1 min -1)和堆肥(791 mg g -1 min -1)可获得最快的吸附速率。)。平衡吸附实验的结果适用于Langmuir和Freundlich等温线,对泥炭(约22 mg g -1)和堆肥(约9 mg g -1)观察到最高吸附容量。解吸实验表明,泥炭和堆肥吸附更多的镍,并且在暴露于无镍溶液中也释放出较低百分比的吸附金属。