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Sm3+-doped strontium barium borate phosphor for white light emission: spectroscopic properties and Judd–Ofelt analysis
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.3 ) Pub Date : 2020-11-14 , DOI: 10.1016/j.saa.2020.119187
Sunil Thomas , Rani George , Naser Qamhieh , K.G. Gopchandran , Saleh T. Mahmoud , Alessia Quatela

This study aims to explore the spectroscopic properties of a Sr1.0Ba2.0B6O12:0.5Sm3+ phosphor synthesized using the solid-state reaction method. The morphology and elemental composition of the phosphor were determined using scanning electron microscopy and energy-dispersive X-ray spectroscopy, respectively. Phase changes and crystallite phases in the phosphor were studied using differential-scanning calorimetry and X-ray diffraction, respectively. Raman and Fourier-transform infrared spectra were used to identify the molecular vibrations in the phosphor. The energy bandgap and bonding nature of the phosphor were analyzed using the absorption spectrum. The nephelauxetic ratios determined from the absorption peaks revealed the presence of both ionic and covalent bonding in the phosphor. Judd–Ofelt parameters, along with radiative properties of the phosphor, were evaluated using the peaks in the absorption spectrum. Colorimetric analysis using the photoluminescence spectrum showed that the Sr1.0Ba2.0B6O12:0.5Sm3+ phosphor emits a cool-white light. The higher values of the spectroscopic quality factor, stimulated-emission cross-section, quantum efficiency, and the white-light emission of the phosphor suggest that Sr1.0Ba2.0B6O12:0.5Sm3+ is useful for display and lighting applications.



中文翻译:

掺Sm 3+的硼酸锶钡磷光体用于白光发射:光谱性质和Judd-Ofelt分析

这项研究旨在探索Sr 1.0 Ba 2.0 B 6 O 12:0.5Sm 3+的光谱性质用固态反应法合成的荧光粉。分别使用扫描电子显微镜和能量色散X射线光谱法测定了磷光体的形貌和元素组成。分别使用差示扫描量热法和X射线衍射研究了磷光体中的相变和微晶相。拉曼光谱和傅立叶变换红外光谱用于鉴定磷光体中的分子振动。使用吸收光谱分析了磷光体的能带隙和键合性质。由吸收峰确定的浊度比表明磷光体中存在离子键和共价键。使用吸收光谱中的峰评估了Judd-Ofelt参数以及磷光体的辐射特性。1.0 Ba 2.0 B 6 O 12:0.5Sm 3+磷光体发出冷白色光。光谱质量因数,激发发射截面,量子效率和磷光体的白光发射值较高,表明Sr 1.0 Ba 2.0 B 6 O 12:0.5Sm 3+可用于显示和照明应用。

更新日期:2020-11-15
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