Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge,Inorganic Chemistry Frontiers

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Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2020-10-30 , DOI: 10.1039/d0qi00924e
Zhaohong Miao _{1,

2,

3,

4,

5} , Yun Yang _{1,

2,

3,

4} , Zhonglei Wei _{1,

2,

3,

4,

5} , Zhihua Yang _{1,

2,

3,

4} , Shilie Pan _{1,

2,

3,

4}

Affiliation

A new member in the barium fluorooxoborate family, namely Ba₂B₇O₁₂F, was obtained by the high-temperature solution method in an open system under ambient pressure. The structure features a new fundamental building block [B₇O₁₆F], which interconnects with each other to form the anionic framework [B₇O₁₂F]_∞ with two different caves in which the cations reside. The experiment result indicates that Ba₂B₇O₁₂F possesses a deep-ultraviolet cut-off edge below 180 nm.

中文翻译：

具有新型FBB [B7O16F]和深紫外线切割边缘的Ba2B7O12F

氟氧硼酸钡族的新成员，即Ba ₂ B ₇ O ₁₂ F，是在室温下在开放系统中通过高温溶液法获得的。该结构具有一个新的基本结构单元[B ₇ O ₁₆ F]，该结构单元相互连接以形成阴离子骨架[B ₇ O ₁₂ F] _∞，该结构带有两个驻留阳离子的不同空穴。实验结果表明，Ba ₂ B ₇ O ₁₂ F在180 nm以下具有深紫外线截止边缘。

更新日期：2020-11-13

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