当前位置: X-MOL 学术Front. Phys. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Fe-Vacancy-Ordered Fe4Se5: The Insulating Parent Phase of FeSe Superconductor
Frontiers in Physics ( IF 1.9 ) Pub Date : 2020-09-30 , DOI: 10.3389/fphy.2020.567054
Keng-Yu Yeh , Yan-Ruei Chen , Tung-Sheng Lo , Phillip M. Wu , Ming-Jye Wang , Kuei-Shu Chang-Liao , Maw-Kuen Wu

We carried out a detailed study to investigate the existence of an insulating parent phase for FeSe superconductors. The insulating Fe4Se5 with √5 × √5 Fe-vacancy order shows a 3D-Mott variable-range-hopping behavior with a Verwey-like electronic correlation at around 45 K. The application of the RTA process at 450°C results in the destruction of Fe-vacancy order and induces more electron carriers by increasing the Fe3+ valence state. Superconductivity emerges with Tc ∼ 8 K without changing the chemical stoichiometry of the sample after the RTA process, resulting in the addition of extra carriers in favor of superconductivity.



中文翻译:

铁空位排列的Fe4Se5:FeSe超导体的绝缘母相

我们进行了详细的研究,以研究FeSe超导体的绝缘母相的存在。具有√5×√5Fe空位顺序的绝缘Fe 4 Se 5表现出3D-Mott变程跳跃行为,在45 K左右具有类似Verwey的电子相关性。RTA工艺在450°C下的应用结果通过破坏Fe 3+价态,可以消除Fe的空位,并诱导更多的电子载流子。超导出现Ťc〜8 K且在RTA处理后不改变样品的化学计量,导致添加了额外的有利于超导的载流子。

更新日期:2020-11-13
down
wechat
bug