Chiral iodoarenes have been steadily increasing in importance in recent years, especially in enantioselective synthesis and catalysis. Since the development of the concept of chiral iodine(I/III) catalysis, the use of various chiral aryliodine frameworks has been explored in this area. This short review gives an overview of the use of chiral hypervalent iodine(I/III) reagents based on the 2-iodoresorcinol core with two attached two lactic side chains bearing ester or amide groups for the catalytic enantioselective dearomatization of phenol compounds, asymmetric oxidation of alkenes, and enantioselective α-functionalization of carbonyl compounds highlighting the excellent reactivities in terms of yield and enantioselectivity.

1 Introduction

2 Enantioselective Dearomatization of Phenol Derivatives

3 Asymmetric Oxidation of Alkenes

4 Enantioselective α-Functionalization of Carbonyl Compounds

5 Conclusion and Outlook

近年来，手性碘代芳烃的重要性一直在稳步提高，特别是在对映选择性合成和催化方面。自从手性碘（I / III）催化概念的发展以来，在这一领域中已探索了各种手性阿里碘的骨架的使用。这篇简短的综述概述了使用基于2-异戊二烯核心的手性高价碘（I / III）试剂，其中两个带有两个带有酯或酰胺基的乳酸侧链，用于酚类化合物的催化对映选择性脱芳香化，烯烃和羰基化合物的对映选择性α-官能化突出了在收率和对映选择性方面的出色反应性。

1引言

2苯酚衍生物的对映选择性脱芳香化

3烯烃的不对称氧化

4羰基化合物的对映选择性α-官能化

5结论与展望