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High temperature and low voltage AC poling for 0.24Pb(In1/2Nb1/2)O3-0.46Pb(Mg1/3Nb2/3)O3-0.30PbTiO3 piezoelectric single crystals manufactured by continuous-feeding Bridgman method
Journal of Materiomics ( IF 8.4 ) Pub Date : 2020-11-13 , DOI: 10.1016/j.jmat.2020.11.003
Cong Luo , Tomoaki Karaki , Yohachi (John) Yamashita , Jiayue Xu

Alternating current poling (ACP) in air by changing poling temperature (70–130 °C) and voltages (2–6 kVrms/cm) on pseudo-ternary 0.24 Pb(In1/2Nb1/2)O3-0.46 Pb(Mg1/3Nb2/3)O3-0.30PbTiO3 (PIMN-0.30PT) single crystals (SCs) manufactured by continuous-feeding Bridgman (CF BM) method was investigated. Free dielectric permittivity (εT33/ε0) and piezoelectric constant (d33) were improved to be 7000 and 2340 pC/N, which were 29% higher than those of direct current poling (DCP) at 90 °C with 4 kV/cm (εT33/ε0 = 5440, d33 = 1810 pC/N). However, phase change temperature (Tpc) decreased from 94 °C to 78 °C as opposite results reported by other groups. We demonstrated that the high temperature (HT) ACP improved piezoelectric performance of CF BM SCs, however, the Tpc were different from other crystal growth method. The well-designed ACP process was a promising method for mass production not only to enhance the electrical properties for the pseudo-ternary SCs but also reduce the risk of breakdown and realizes organic solvent-free poling process.



中文翻译:

通过连续进给Bridgman制造的0.24Pb(In 1/2 Nb 1/2)O 3 -0.46Pb(Mg 1/3 Nb 2/3)O 3 -0.30PbTiO 3压电单晶的高温低压AC极化方法

通过更改伪三元0.24 Pb(In 1/2 Nb 1/2)O 3 -0.46 Pb上的极化温度(70–130°C)和电压(2–6 kVrms / cm)改变空气中的极化电流(ACP)研究了通过连续喂入布里奇曼法(CF BM)制备的(Mg 1/3 Nb 2/3)O 3 -0.30PbTiO 3(PIMN-0.30PT)单晶(SCs)。自由介电常数(ε Ť 33 / ε 0)和压电常数(d 33)被提高到7000和2340 PC / N,均较直流极化(DCP)的高29%,在90℃下用4千伏/厘米(ε Ť33 / ε 0  = 5440,d 33  = 1810 PC / N)。但是,相变温度(T pc)从94°C降低到78°C,这与其他小组报告的结果相反。我们证明了高温(HT)ACP可以改善CF BM SC的压电性能,但是T pc与其他晶体生长方法不同。精心设计的ACP工艺是一种有前途的批量生产方法,不仅可以增强伪三元SC的电性能,而且还可以降低击穿风险并实现无有机溶剂的极化工艺。

更新日期:2020-11-13
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