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Synthesis of a copper hydroxystannate modified graphene oxide nanohybrid and its high performance in flexible polyvinyl chloride with simultaneously improved flame retardancy, smoke suppression and mechanical properties
Polymer Degradation and Stability ( IF 5.9 ) Pub Date : 2020-11-13 , DOI: 10.1016/j.polymdegradstab.2020.109425
Zhenyu Huang , Zhengzhou Wang

A copper hydroxystannate (CHS) modified graphene oxide (GO) nanohybrid (CGO) was synthesized through one step in-situ technique, and characterized by transmission electronic microscopy, energy dispersive X-ray spectrometry, X-ray diffractometer, etc. Flexible polyvinyl chloride (FPVC) containing CGO demonstrates remarkable mechanical, thermal and flame retardant properties. FPVC with 2 wt% CGO (sample FPVC/2CGO) achieves V0 rating in the UL-94 test with a limiting oxygen index of 26.5%. The cone calorimeter test results exhibit that the peak heat release rate, total smoke release, carbon monoxide production rate and carbon dioxide production rate of sample FPVC/2CGO were reduced by 44.5%, 20.4%, 29.6% and 45.3%, respectively in comparison with the ones of pure FPVC. Moreover, the tensile strength and the elongation at break of sample FPVC/2CGO are higher than the ones of pure FPVC.



中文翻译:

羟基锡酸铜修饰的氧化石墨烯纳米杂合物的合成及其在柔性聚氯乙烯中的高性能,同时提高了阻燃性,抑烟性和机械性能

通过一步原位合成了羟基锡酸铜(CHS)修饰的氧化石墨烯(GO)纳米杂化体,并通过透射电子显微镜,能量色散X射线光谱法,X射线衍射仪等进行了表征。柔性聚氯乙烯含有CGO的(FPVC)具有出色的机械,热和阻燃性能。具有2 wt%CGO的FPVC(样品FPVC / 2CGO)在UL-94测试中达到V0等级,极限氧指数为26.5%。锥形量热仪测试结果表明,与FPVC / 2CGO相比,样品的峰值放热率,总烟气释放量,一氧化碳产生率和二氧化碳产生率分别降低了44.5%,20.4%,29.6%和45.3%。纯FPVC的。此外,

更新日期:2020-11-13
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