Using experimental and computational approaches to probe an unusual carbon–carbon bond cleavage observed in the synthesis of benzimidazole N-oxides,Organic & Biomolecular Chemistry

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Using experimental and computational approaches to probe an unusual carbon–carbon bond cleavage observed in the synthesis of benzimidazole N-oxides
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020-11-06 , DOI: 10.1039/d0ob01797c
Fabrizio Politano _{1,

2,

3,

4,

5} , Arturo León Sandoval _{1,

2,

3,

4} , Jorge G. Uranga _{5,

6,

7,

8,

9} , Elba I. Buján _{5,

6,

7,

8,

9} , Nicholas E. Leadbeater _{1,

2,

3,

4}

Affiliation

Experimental and computational studies have been performed in order to investigate an unusual carbon–carbon bond cleavage that occurs in the preparation of certain benzimidazole N-oxides from anilines. The key factor determining the outcome of the reaction was found to be the substituents on the amine functionality of the aniline.

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