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Kinetic-model-based design of industrial reactor for catalytic hydrogen production via ammonia decomposition
Chemical Engineering Research and Design ( IF 3.7 ) Pub Date : 2020-11-12 , DOI: 10.1016/j.cherd.2020.11.004
Atsushi Takahashi , Tadahiro Fujitani

A two-dimensional reactor model based on reaction kinetics and heat and mass transfer for catalytic NH3 decomposition was constructed. A reactor design that minimizes the effect of endothermic reaction was investigated. It is difficult to design a single-tube reactor for NH3 treatment at a flow rate of 10 m3/h because heat transfer from the reactor wall cannot keep up with the fast consumption of heat by the reaction, even under low space velocity conditions. The target conversion was achieved by decreasing the NH3 supply rate. A reactor with a packed bed of suitable length was designed. Industrial-scale NH3 treatment can be achieved using a multi-tube reactor.



中文翻译:

基于动力学模型的氨分解工业制氢反应器设计

建立了基于反应动力学和传热传质的NH 3催化分解二维反应器模型。研究了使吸热反应的影响最小化的反应器设计。难以设计以10 m 3 / h的流速处理NH 3的单管反应器,因为即使在低空速条件下,从反应器壁传热也无法跟上反应的快速热量消耗。 。通过降低NH 3供给速率实现了目标转化率。设计了具有合适长度的填充床的反应器。使用多管反应器可以实现工业规模的NH 3处理。

更新日期:2020-12-01
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