Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

生物燃料合成对于生产替代燃料具有重要意义。在已开发的催化材料中，用作酸性，碱性或负载型催化剂的基于金属-有机骨架的杂化物在生物柴油生产中起主要作用。本文对来自各种石油原料的生物柴油合成所用的金属-有机骨架催化剂的设计和制备进行了及时，全面的回顾，包括基于MILS的催化剂，ZIFs的催化剂，UiO的催化剂，Cu -基于BTC的催化剂和MOF衍生的多孔催化剂。与其他非均相催化剂相比，由于其独特而灵活的结构，出色的热稳定性和水热稳定性以及可调节的主客体相互作用，