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Effect of cyclic reprocessing on nylon 12 under injection moulding: working towards more efficient recycling of plastic waste
Materials Today Sustainability ( IF 7.8 ) Pub Date : 2020-11-07 , DOI: 10.1016/j.mtsust.2020.100056
M.S. Nur-A-Tomal , F. Pahlevani , W. Handoko , S.T. Cholake , V. Sahajwalla

Due to the limitations that impede traditional recycling technologies, only a small percentage of waste plastic are currently recycled. Most recycling processes create products that are poor in terms of performance and value. To produce high-quality products from plastic waste and bringing back these valuable materials to the economy after their end-of-life, it is important to know the change in polymer properties during cyclic reprocessing. During this study, investigations were conducted to create a profound understanding of the effects of cyclic reprocessing on the properties of nylon 12. First, the flow behaviour of molten nylon 12 in injection mould was studied. Then, optimised processing conditions were established by investigating the tensile and impact strength of moulded products. Finally, the influence of cyclic reprocessing on the material was assessed through tensile test, impact test, thermal analysis, X-ray diffractometry (XRD) and Fourier transform infrared (FTIR) spectroscopy. The obtained results indicate that nylon 12 could be recycled at least four times without drastically changing its properties. A slight decrease in the tensile strength, impact strength, glass transition temperature and percentage crystallinity was observed as the number of reprocessing cycles increases. Furthermore, no significant variation of FTIR spectra indicated that multiple reprocessing had not changed the molecular structure of nylon 12. Together, the various elements of this research could be helpful in developing more effective and efficient recycling processes for plastic waste.



中文翻译:

循环处理对注塑成型的尼龙12的影响:致力于更有效地回收塑料废料

由于阻碍传统回收技术的局限性,目前仅回收一小部分废塑料。大多数回收过程所产生的产品在性能和价值上都很差。为了从塑料废料生产高质量的产品,并将这些有价值的材料在使用寿命到期后重新带回经济,了解循环再加工过程中聚合物性能的变化非常重要。在这项研究过程中,进行了研究以深刻理解循环再加工对尼龙12性能的影响。首先,研究了熔融尼龙12在注塑模具中的流动行为。然后,通过研究模制品的拉伸强度和冲击强度来确定最佳的加工条件。最后,通过拉伸试验,冲击试验,热分析,X射线衍射(XRD)和傅里叶变换红外(FTIR)光谱评估了循环后处理对材料的影响。所得结果表明,尼龙12可以循环使用至少四次而不会显着改变其性能。随着后处理循环次数的增加,拉伸强度,冲击强度,玻璃化转变温度和结晶度百分比略有下降。此外,FTIR光谱没有显着变化,表明多次后处理并没有改变尼龙12的分子结构。综上所述,这项研究的各个要素可能有助于开发更有效的塑料废物回收方法。热分析,X射线衍射(XRD)和傅立叶变换红外(FTIR)光谱。所得结果表明,尼龙12可以循环使用至少四次而不会显着改变其性能。随着后处理循环次数的增加,拉伸强度,冲击强度,玻璃化转变温度和结晶度百分比略有下降。此外,FTIR光谱没有显着变化,表明多次后处理并没有改变尼龙12的分子结构。综上所述,这项研究的各个要素可能有助于开发更有效的塑料废物回收方法。热分析,X射线衍射(XRD)和傅立叶变换红外(FTIR)光谱。所得结果表明,尼龙12可以循环使用至少四次而不会显着改变其性能。随着后处理循环次数的增加,拉伸强度,冲击强度,玻璃化转变温度和结晶度百分比略有下降。此外,FTIR光谱没有显着变化,表明多次后处理并没有改变尼龙12的分子结构。综上所述,这项研究的各个要素可能有助于开发更有效的塑料废物回收方法。所得结果表明,尼龙12可以循环使用至少四次而不会显着改变其性能。随着后处理循环次数的增加,拉伸强度,冲击强度,玻璃化转变温度和结晶度百分比略有下降。此外,FTIR光谱没有显着变化,表明多次后处理并没有改变尼龙12的分子结构。综上所述,这项研究的各个要素可能有助于开发更有效的塑料废物回收方法。所得结果表明,尼龙12可以循环使用至少四次而不会显着改变其性能。随着后处理循环次数的增加,拉伸强度,冲击强度,玻璃化转变温度和结晶度百分比略有下降。此外,FTIR光谱没有显着变化,表明多次后处理并没有改变尼龙12的分子结构。综上所述,这项研究的各个要素可能有助于开发更有效的塑料废物回收方法。

更新日期:2020-11-09
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