The combinations of microflow technology and photo-induced reversible-addition fragmentation chain transfer polymerization (photo-RAFT) and light-mediated polymerization-induced self-assembly (light-PISA) have enabled distinguished advantages that cannot be done in the traditional batch reactor. Recently, well-defined polymers with precise chemical and topological structures, and advanced nano-objects with high-order morphologies have been reported by using microreactor-based photo-RAFT and light-PISA strategies. In this mini-review, continuous flow photoiniferter polymerization, RAFT with photoinitiator, and PET-RAFT are summarized in order. Moreover, the emerging light-PISA in microflow is introduced, and finally, the remained challenges are proposed for the discussion of opportunities. We hope it would provide insights into flow chemistry, polymer precision synthesis, and nanoscience.

微流技术与光诱导的可逆加成断裂链转移聚合（photo-RAFT）和光介导的聚合诱导的自组装（light-PISA）的结合已实现了传统分批反应器无法实现的显着优势。近来，通过使用基于微反应器的photo-RAFT和light-PISA策略，已经报道了定义精确的具有精确化学和拓扑结构的聚合物，以及具有高阶形态的先进纳米物体。在本微型综述中，按顺序总结了连续流动光引发剂聚合，带有光引发剂的RAFT和PET-RAFT。此外，介绍了微流中新兴的轻型PISA，最后，提出了尚待解决的挑战以讨论机会。我们希望它能提供有关流动化学的见解，