The template synthesis of novel bis-tetrabenzoporphyrin complexes of gadolinium, erbium and lutetium is described. The structure of these sandwich-type complexes was confirmed by the elemental analysis, MALDI-TOF mass spectrometry and optical spectroscopy in the visible, near and middle infrared range. The electrochemical behavior was studied by the cyclic voltammetry and compared to that of the structurally similar bis-phthalocyanine lanthanides. The conductivity of thin films of bis-tetrabenzoporphyrin complexes was measured both in the dark and under illumination. Thin films of erbium complex showed the highest photosensitivity, while the films of the gadolinium complex have the lowest resistivity.

描述了novel，和的新型双-四苯并卟啉配合物的模板合成。这些夹心型配合物的结构通过可见光，近红外和中红外范围内的元素分析，MALDI-TOF质谱和光学光谱确认。通过循环伏安法研究了电化学行为，并将其与结构相似的双酞菁镧系元素的电化学行为进行了比较。双-四苯并卟啉配合物薄膜的电导率在黑暗和光照条件下均可测量。complex配合物薄膜显示出最高的光敏性，而complex配合物薄膜具有最低的电阻率。