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Effect of volume ratio on optical and mechanical properties of Y2O3-MgO composites fabricated by spark-plasma-sintering process
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-11-04 , DOI: 10.1016/j.jeurceramsoc.2020.10.074
Lihong Liu , Koji Morita , Tohru S. Suzuki , Byung-Nam Kim

The effect of Y2O3:MgO ratio on the microstructures, optical and mechanical properties of the Y2O3-MgO composites were investigated. Although the dense Y2O3-MgO composites were successfully fabricated in various Y2O3:MgO ratios using the spark-plasma-sintering (SPS) technique, the Y2O3:MgO ratio significantly influenced the microstructures and the optical/mechanical properties of the composites. Fine grain size was obtained in the composite with Y2O3:MgO = 50:50 owing to the effective pinning force caused by the homogenous two phase microstructure. The SPSed dense composites showed good transmittance in the wide wavelength range from visible to infrared (IR). The monolithic Y2O3 polycrystal, that is Y2O3:MgO = 100:0, showed the highest transmittance of 62.3 % at 600 nm and 84.3 % at 5 μm. Although the IR transmittance is independent of the Y2O3:MgO ratio, the visible transmittance decreased with the MgO particle dispersion. Among the Y2O3-MgO composites, the higher visible transmittance was obtained in the composite with Y2O3:MgO = 50:50 than those of the other two composites with Y2O3:MgO = 30:70 and 70:30 due to its smallest grain size. In contrast to the transmittance, the hardness Hv and toughness KIC tend to increase with increasing the MgO fraction irrespective of the grain size; both Hv and KIC increased from 9.6 GPa and 1.1 MPa m1/2 for the monolithic Y2O3 to 12.7 GPa and 2.5 MPa m1/2 for the composite with Y2O3/MgO = 30:70, respectively. The enhanced hardness and toughness of the composite can be interpreted dominantly by the mixture rule as a function of the volume fraction of the MgO phase.



中文翻译:

体积比对火花等离子体烧结制备Y 2 O 3 -MgO复合材料光学和力学性能的影响

研究了Y 2 O 3:MgO比对Y 2 O 3 -MgO复合材料的微观结构,光学和力学性能的影响。尽管使用火花等离子体烧结(SPS)技术成功地以各种Y 2 O 3:MgO比率成功制备了致密的Y 2 O 3 -MgO复合材料,但Y 2 O 3:MgO比率显着影响了微观结构和光学/复合材料的机械性能。在具有Y 2 O 3的复合物中获得了细晶粒度:MgO = 50:50是由于均质的两相微结构引起的有效钉扎力。SPSed致密复合材料在从可见光到红外(IR)的宽波长范围内均显示出良好的透射率。Y 2 O 3:MgO = 100:0的单片Y 2 O 3多晶体在600 nm处显示最高透射率,在5μm处显示最高透射率,为84.3%。尽管IR透射率与Y 2 O 3:MgO比无关,但是可见透射率随着MgO颗粒分散而降低。在Y 2 O 3 -MgO复合材料中,具有Y 2 O 3的复合材料具有较高的可见光透射率。:MgO = 50:50比Y 2 O 3:MgO = 30:70和70:30的其他两种复合材料的晶粒尺寸最小。与透射率相反,无论晶粒大小如何,随着MgO含量的增加,硬度H v和韧性K IC趋于增加。既ħ vķ IC从9.6 GPA和1.1兆帕米增加1/2为单片ÿ 2 ö 3至12.7 GPA和2.5兆帕米1/2为复合,其中Y 2 ö 3/ MgO分别为30:70。复合材料增强的硬度和韧性可以通过混合规则主要解释为MgO相体积分数的函数。

更新日期:2020-12-01
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