Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-11-04 , DOI: 10.1016/j.cplett.2020.138157 Jinteng Zhang , Peng Zhao , Yingchen Li , Yuehong Cao , Tengfeng Xie , Yanhong Lin , Zhao Mu
A series of novel porous center-hollow ZnO/ZnSe microspheres were synthesized via two-step hydrothermal and ion-exchange method. It is found the load of ZnSe improves photocatalytic activity of the nanocomposites and ZSe-3 sample shows the most prominent performance, 88.8% of Cr(VI) can be reduced in 60 min under the irradiation of visible light (λ > 420 nm). ZnSe nanoparticles can be used to sensitize the ZnO microspheres and further extend the visible light response range. The n-p heterojunction formed at the interface between ZnO and ZnSe can also contribute to improve the separation and transfer properties of charge carriers in ZnO.
中文翻译:
借助ZnO / ZnSe分级np异质结增强可见光驱动的Cr(VI)还原
通过两步水热和离子交换法合成了一系列新颖的多孔中心空心ZnO / ZnSe微球。发现ZnSe的负载改善了纳米复合材料的光催化活性,ZSe-3样品表现出最突出的性能,在可见光(λ> 420 nm)照射下60分钟内可以还原88.8%的Cr(VI)。ZnSe纳米颗粒可用于敏化ZnO微球并进一步扩展可见光响应范围。在ZnO和ZnSe之间的界面处形成的np异质结也有助于改善ZnO中电荷载流子的分离和转移特性。