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Melamine/polyaniline-derived carbons with record-high adsorption capacities for effective removal of phenolic compounds from water
Chemical Engineering Journal ( IF 13.3 ) Pub Date : 2020-11-05 , DOI: 10.1016/j.cej.2020.127627
Jong Min Park , Chang Min Kim , Sung Hwa Jhung

Recently, contamination of water resources with phenolic compounds (PCs) is severe. In this study, we firstly prepared nitrogen-enriched porous carbon via pyrolysis of a mixture of melamine and polyaniline. Melamine/polyaniline-derived carbons (MPDCs) were characterized and applied in the adsorption of PCs, like p-nitrophenol (pNP), hydroquinone (HQ) and p-cresol (pC), from water. A selected MPDC700, an MPDC prepared at 700 oC, had the highest adsorption capacity for pNP (Qmax: 910±18 mg/g) and pC, compared with any known material. Based on the adsorption results under wide conditions and characteristics of MPDCs, the plausible adsorption mechanism, such as π-π interaction and hydrogen bonding, could be suggested. The best MPDC700 was recyclable for several runs; therefore, can be recommended as a competitive adsorbent to remove PCs from water.



中文翻译:

三聚氰胺/聚苯胺衍生的碳具有创纪录的高吸附能力,可有效去除水中的酚类化合物

最近,酚类化合物(PC)对水资源的污染严重。在这项研究中,我们首先通过热分解三聚氰胺和聚苯胺的混合物制备了富氮多孔碳。对三聚氰胺/聚苯胺衍生的碳(MPDC)进行了表征,并将其应用于从水中吸附PC,例如硝基苯酚(pNP),对苯二酚(HQ)和甲酚(pC)。选定的MPDC700(在700 o C下制备的MPDC)对pNP的吸附能力最高(Q max:910±18 mg / g)和pC,与任何已知材料相比。根据在大范围条件下的吸附结果和MPDC的特性,可以提出合理的吸附机理,如π-π相互作用和氢键。最好的MPDC700可循环使用多次。因此,可以推荐作为从水中去除PC的竞争性吸附剂。

更新日期:2020-11-06
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