当前位置: X-MOL 学术J. Electron. Mater. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Enhanced Capacitive Performance of Manganese Oxide/Mesoporous Carbon Composite Film Electrodes
Journal of Electronic Materials ( IF 2.2 ) Pub Date : 2020-11-05 , DOI: 10.1007/s11664-020-08550-8
Mahanim Sarif , Zulkarnain Zainal , Mohd Zobir Hussein , Mohd Haniff Wahid , Noor Nazihah Bahrudin

Manganese(III) oxide/mesoporous carbon (Mn2O3/MPC) composite films for supercapacitor electrodes have been synthesized using the incipient wetness impregnation method. Mn2O3 was polymerized on MPC film using resorcinol (R) and formaldehyde (F) as carbon precursors, and Pluronic F127 as template. X-ray diffraction analysis, Fourier-transform infrared spectroscopy, Raman spectroscopy, x-ray photoelectron spectroscopy, and field-emission scanning electron microscopy were conducted to observe the structure and surface morphology of Mn2O3/MPC. Cyclic voltammetry and galvanostatic charge–discharge measurements were performed in 1 M potassium chloride electrolyte. Mn2O3/MPC composite film showed a specific capacitance 3.5 times larger than that of MPC film (53.59 mF cm−2 versus 15.23 mF cm−2). The increased capacitance was due to the combination of electrical properties of MPC film and the pseudocapacitive characteristics of manganese oxide. Mn2O3/MPC composite film showed fairly stable capacitance with approximately 71% retention after 1000 cycles of stability test, compared with 98% for MPC.



中文翻译:

氧化锰/中孔碳复合膜电极的增强电容性能

采用初期湿润浸渍法合成了用于超级电容器电极的氧化锰(III)/介孔碳(Mn 2 O 3 / MPC)复合膜。以间苯二酚(R)和甲醛(F)为碳前体,以Pluronic F127为模板,在MPC膜上聚合Mn 2 O 3。进行了X射线衍射分析,傅立叶变换红外光谱,拉曼光谱,X射线光电子能谱和场发射扫描电子显微镜观察Mn 2 O 3 / MPC的结构和表面形态。循环伏安法和恒电流充放电测量是在1 M氯化钾电解质中进行的。锰2O 3 / MPC复合膜的比电容是MPC膜的比电容的3.5倍(53.59 mF cm -2对15.23 mF cm -2)。电容的增加归因于MPC膜的电性能和氧化锰的假电容特性的结合。Mn 2 O 3 / MPC复合膜在1000次稳定性测试后显示出相当稳定的电容,保留率约为71%,而MPC为98%。

更新日期:2020-11-05
down
wechat
bug