Recent progress on selective deconstructive modes of halodifluoromethyl and trifluoromethyl-containing reagents,Chemical Society Reviews

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Recent progress on selective deconstructive modes of halodifluoromethyl and trifluoromethyl-containing reagents
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-11-04 , DOI: 10.1039/d0cs00604a
Xingxing Ma _{1,

2,

3,

4,

5} , Qiuling Song _{1,

2,

3,

4,

5}

Affiliation

Halodifluoromethyl and trifluoromethyl-containing compounds are widely employed in organic chemistry, pharmaceuticals and materials science. Therefore, their applications and transformations have received significant attention during the past few decades. The single, double, triple and quadruple cleavage of halodifluoromethyl compounds and various deconstructive modes of trifluoromethyl-containing compounds could generate a variety of synthons to prepare more valuable products. Herein, we summarize the most significant achievements in this field with an intriguing focus on results from the last decade.

中文翻译：

含卤代二氟甲基和三氟甲基试剂的选择性解构模式的最新进展

含卤代二氟甲基和三氟甲基的化合物广泛用于有机化学，药物和材料科学中。因此，在过去的几十年中，它们的应用和转换受到了极大的关注。卤代二氟甲基化合物的单，双，三和四重裂解以及含三氟甲基化合物的各种解构模式可以产生各种合成子以制备更有价值的产品。在此，我们总结了该领域最重要的成就，并着重介绍了过去十年的成果。

更新日期：2020-11-04

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