Synthesis of Indolo[2,1‐a]isoquinolin‐6(5H)‐Ones Derivatives via Fe(OTf)3‐Promoted Tandem Selenylation/Cyclization of 2‐Arylindoles,Advanced Synthesis & Catalysis

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Synthesis of Indolo[2,1‐a]isoquinolin‐6(5H)‐Ones Derivatives via Fe(OTf)3‐Promoted Tandem Selenylation/Cyclization of 2‐Arylindoles
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-11-03 , DOI: 10.1002/adsc.202000983
Jia‐Rong Zhang ₁ , Hao‐Yang Liu ₁ , Tao Fan ₁ , Yan‐Yan Chen ₁ , Yan‐Li Xu ₁

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A practical method for the synthesis of selenylsubstituted indolo[2,1‐a]isoquinolin‐6(5H)‐ones through Fe(OTf)₃‐promoted tandem selenylation/cyclization of 2‐arylindoles was developed. In this transformation, new C−Se bond and C−C bond were constructed simultaneously under mild conditions.

中文翻译：

Fe（OTf）3促进的2-Arylindoles串联硒化/环化反应合成Indolo [2,1-a]异喹啉-6（5H）-Ones衍生物

开发了一种实用的方法，通过Fe（OTf）₃促进的2-芳基吲哚的串联硒化/环化反应合成硒基取代的吲哚[2,1 - a ]异喹啉-6（5 H）-酮。在此转变中，在温和条件下同时构建了新的C-Se键和C-C键。

更新日期：2020-11-03

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