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Cover Feature: Acetylacetonate and Acetate Complexes of Nickel(II) Catalyse the Air Oxidation of Phosphines (Eur. J. Inorg. Chem. 44/2020)
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-11-04 , DOI: 10.1002/ejic.202000990 Line Sofie Hansen 1 , Vibe Boel Jakobsen 1 , Vickie McKee 1 , Christine J. McKenzie 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-11-04 , DOI: 10.1002/ejic.202000990 Line Sofie Hansen 1 , Vibe Boel Jakobsen 1 , Vickie McKee 1 , Christine J. McKenzie 1
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The Cover Feature shows a Ferris wheel as a metaphor for the simple nickel complexes of acac and acetate, which catalyse oxygenation of dppe by O2 directly from air. The reaction is inhibited by insoluble 1D coordination polymer formation: first by a metastable phase containing the substrate bridging between Ni centers, and finally by a phase containing the diphosphine‐dioxide product. Inhibition by product means that the ride is for just a few turns – just like the reaction. Cover design by Dr. Vibe Jakobsen. More information can be found in the Full Paper by C. J. McKenzie et al.
中文翻译：
封面功能：镍（II）的乙酰丙酮酸酯和乙酸酯配合物催化膦的空气氧化（Eur。J. Inorg。Chem。44/2020）
封面功能显示了一个摩天轮，作为acac和醋酸盐的简单镍络合物的隐喻，它们直接催化空气中O 2氧化dppe 。该反应受不溶性一维配位聚合物形成的抑制：首先是亚稳相包含在Ni中心之间桥接的底物，最后是包含二膦二氧化物产物的相。乘积的抑制意味着行驶只是几圈-就像反应一样。Vibe Jakobsen博士的封面设计。可以在C. J. McKenzie等人的论文全文中找到更多信息。
更新日期：2020-11-23
中文翻译：
封面功能：镍（II）的乙酰丙酮酸酯和乙酸酯配合物催化膦的空气氧化（Eur。J. Inorg。Chem。44/2020）
封面功能显示了一个摩天轮，作为acac和醋酸盐的简单镍络合物的隐喻，它们直接催化空气中O 2氧化dppe 。该反应受不溶性一维配位聚合物形成的抑制：首先是亚稳相包含在Ni中心之间桥接的底物，最后是包含二膦二氧化物产物的相。乘积的抑制意味着行驶只是几圈-就像反应一样。Vibe Jakobsen博士的封面设计。可以在C. J. McKenzie等人的论文全文中找到更多信息。
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