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Influence of erbium oxide on structural, physical, elastic and luminescence properties of rice husk biosilicate zinc borotellurite glasses for laser application
Journal of Non-Crystalline Solids ( IF 3.2 ) Pub Date : 2020-11-03 , DOI: 10.1016/j.jnoncrysol.2020.120467
M.K. Halimah , A.S. Asyikin , S.N. Nazrin , M.F. Faznny

Nowadays, active search for more efficient and improved glass material to be employed as laser host has been take place in order to have laser with enhanced performance. In this research, erbium oxide doped rice husk biosilicate zinc borotellurite glasses have been fabricated successfully via conventional melt quenching technique. XRD pattern reveals that the prepared glasses are amorphous in nature while FTIR spectra records the presence of Si-O-Si, TeO3, BO4 as well as BO3 vibrational groups in the fabricated glasses. Increasing density from 3.3505 g/cm3 to 4.1852 g/cm3 along with the rigidity of the glass as hinted in the values for elastic moduli from 55.0 GPa to 250.0 GPa is caused by the incorporation of erbium oxide that reduce the amount of non-bridging oxygen in the glass matrix. Three bands that are recorded in PL spectra correspond to the violet, blue and green emission.



中文翻译:

氧化对激光应用稻壳生物硅酸锌硼铝铁矿玻璃结构,物理,弹性和发光性能的影响

如今,为了使激光器具有增强的性能,已经在积极寻求用作激光主体的更有效和改进的玻璃材料。在这项研究中,通过常规的熔体淬火技术成功地制造了掺oxide氧化物的稻壳生物硅酸盐锌硼铁矿玻璃。XRD图谱显示所制备的玻璃本质上是非晶态的,而FTIR光谱记录了所制备的玻璃中Si-O-Si,TeO 3,BO 4以及BO 3振动基团的存在。密度从3.3505 g / cm 3增加到4.1852 g / cm 3弹性模量值从55.0 GPa到250.0 GPa所暗示的玻璃刚度,是由于掺入氧化reduce而减少了玻璃基体中非桥连氧的数量所致。PL光谱中记录的三个波段分别对应于紫色,蓝色和绿色发射。

更新日期:2020-11-04
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