Based on photovoltaic effect and annealing,a flexible liquid-solid heterostructure of PANI and PyBIG based on carbon nano-tube (CNT) is prepared to drive the low temperature (343 K-363 K) CO₂ desorption intensified by the light. By the DFT and experiment, the reaction mechanism is determined as electron and hole produced by the light, deprotonization, electron and hole transport, and CO₂ release. The flexible characteristic of the heterostructure is identified as interface slip, transport channel change and stretching phenomenon in the nano-scale. The repelling effect between water molecule and oil molecule enhances the -COO-H bond breaking and -NH₂ production. The stretching phenomenon makes the electron and hole transport along the line rather than in a circle. The CO₂ desorption reaction energy is determined as low as 11.42 kJ/mol. The energy consumption of heterostructure to drive the CO₂ desorption at 343 K-363 K is determined as 0.89 GJ/t-1.12 GJ/t, which is much lower than the conventional 2.2 GJ/t-2.8 GJ/t.

基于光伏效应和退火，制备了基于碳纳米管（CNT）的PANI和PyBIG的柔性液固异质结构，以驱动由光增强的低温（343 K-363 K）CO ₂解吸。通过DFT和实验，反应机理被确定为由光，去质子化，电子和空穴传输以及CO ₂释放产生的电子和空穴。异质结构的柔性特征被识别为纳米级的界面滑移，传输通道变化和拉伸现象。水分子和油分子之间的排斥作用增强了-COO-H键的断裂和-NH ₂生产。拉伸现象使电子和空穴沿着线而不是圆形传输。测定的CO ₂解吸反应能低至11.42kJ / mol。确定在343 K-363 K下驱动CO ₂解吸的异质结构的能量消耗为0.89 GJ / t-1.12 GJ / t，远低于传统的2.2 GJ / t-2.8 GJ / t。