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A 63,65 Cu NMR Study of Cu 1–X Pd x FeS 2 Chalcopyrite Compounds
Journal of Applied Spectroscopy ( IF 0.8 ) Pub Date : 2020-11-04 , DOI: 10.1007/s10812-020-01077-0
V. L. Matukhin , A. N. Gavrilenko , E. V. Schmidt , I. G. Sevastyanov , F. R. Sirazutdinov , J. Navratil , P. Novak

A 63,65Cu NMR study was carried out on a series of Cu1–xPdxFeS2 compounds (x = 0–0.02) in a local magnetic field at 77 K. The spectra of the samples were taken. Their parameters were determined and the fields in the region of 63,65Cu nuclei were estimated. Asymmetric broadening of the NMR resonance lines was found along with a smoother decay in the high-frequency region, which may result from an increase in the amount of defects in the crystal lattice of the compound. These can be FeCu2+ antistructural defects, whose formation is attributed to the generation of the PdS phase in the chalcopyrite matrix with an increase in the nominal Pd content.



中文翻译:

Cu 1–X Pd x FeS 2黄铜矿化合物的63,65 Cu NMR研究

63,65的Cu NMR研究是对一系列的Cu进行1-x的Pd X的FeS 2种取化合物(X = 0-0.02)在局部磁场在77K的样品的光谱。确定了它们的参数并估计了63,65 Cu核区域中的场。发现NMR共振线的不对称加宽以及高频区域的平滑衰减,这可能是由于化合物晶格中缺陷数量的增加所致。这些可能是FeCu 2+的抗结构缺陷,其形成归因于黄铜矿基质中PdS相的产生以及标称Pd含量的增加。

更新日期:2020-11-04
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