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An 80-Carbon Aromatic Saddle Enabled by a Naphthalene-Directed Scholl Reaction
Organic Materials Pub Date : 2020-09-21 , DOI: 10.1055/s-0040-1716499 Sai Ho Pun 1 , Chi Kit Chan 1 , Zhifeng Liu 1 , Qian Miao 1
中文翻译：
萘导向的Scholl反应引发的80碳芳烃鞍
更新日期：2020-11-03
Organic Materials Pub Date : 2020-09-21 , DOI: 10.1055/s-0040-1716499 Sai Ho Pun 1 , Chi Kit Chan 1 , Zhifeng Liu 1 , Qian Miao 1
Affiliation
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Synthesis of an unprecedented aromatic saddle consisting of 80 sp2 carbons is enabled by including naphthylene groups in the substrate of the Scholl reaction. The negatively curved polycyclic framework of this aromatic saddle is revealed by the single crystal X-ray crystallography, and its stereodynamics are studied with density functional theory calculations.
中文翻译：
萘导向的Scholl反应引发的80碳芳烃鞍
通过在Scholl反应的底物中包含亚萘基，可以合成由80个sp 2碳组成的前所未有的芳族鞍。单晶X射线晶体学揭示了该芳族鞍的负弯曲多环骨架，并利用密度泛函理论计算研究了其立体动力学。
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