Results in Chemistry ( IF 2.5 ) Pub Date : 2020-01-31 , DOI: 10.1016/j.rechem.2020.100027 Jiajia Fang , Beina Dong , Yingqiang Fu , Dingxing Tang
Thioglycolic acid-modified CuInS2 quantum dots were prepared by a hydrothermal method. A method for the determination of sparfloxacin by a CuInS2 ternary-quantum dot fluorescence probe was established based on the fact that the fluorescence of CuInS2 quantum dots can be significantly quenched by sparfloxacin. The optimized experimental conditions are as follows: (1) the concentration of CuInS2 quantum dots is 0.4 mol·L−1; (2) the pH of the buffer solution is 6, and 1 mL of buffer was used; (3) the reaction time is 5 min. The concentration of sparfloxacin is linearly related to the fluorescence quenching intensity from 0.5 μg/mL to 1 mg/mL, and the maximum detection limit is 1 mg/mL.
中文翻译:
基于水溶性CuInS 2量子点的司帕沙星检测
通过水热法制备巯基乙酸修饰的CuInS 2量子点。基于CuInS 2三元量子点荧光探针可以有效地淬灭CuInS 2量子点的荧光这一事实,建立了一种用CuInS 2三元量子点荧光探针测定司帕沙星的方法。优化的实验条件如下:(1)CuInS 2量子点的浓度为0.4mol·L - 1;(2)缓冲溶液的pH为6,使用1mL缓冲液。(3)反应时间为5分钟。司帕沙星的浓度与荧光猝灭强度从0.5μg/ mL到1 mg / mL呈线性关系,最大检出限为1 mg / mL。