Applications of diazaphospholene hydrides in chemical catalysis,Chemical Society Reviews

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Applications of diazaphospholene hydrides in chemical catalysis
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-10-20 , DOI: 10.1039/d0cs00476f
Alexander W. H. Speed _{1,

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Affiliation

Diazaphospholenes have recently emerged as main-group hydride transfer catalysts. This review will briefly summarize the common structural variants of diazaphospholenes, and the properties that make them superb hydride transfer catalysts, followed by a critical examination of the various preparative routes toward diazaphospholenes. Finally, an in-depth examination of the reactivity of diazaphospholenes in contemporary catalysis, including asymmetric catalysis will be undertaken.

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