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Photoluminescence properties of Eu3+-activated Y1.50Sc0.50O3 phosphors
Indian Journal of Chemistry, Section A Pub Date : 2020-11-02
Erkul Karacaoglu, Esra Öztürk

In this research, Eu3+ activated and Dy3+-co-doped Y2O3 based phosphors have been synthesized by solid-state reaction method under open atmosphere. The host lattice is composed of 0.25 moles of Sc2O3 which is added to phosphor composition. Thus, Sc3+ substitution of Y3+ ions is implemented to form Y1.40Sc0.50O3 host lattice. The thermal analysis (DTA/TG) have been carried out from 50 °C to 1400 °C for preliminary examination of thermal behavior of phosphors during heat treatments. After the heating process, the phase formations are characterized by X-ray diffraction resulted as Y2O3 single phase cubic structure. The effects of Eu3+ and Dy3+ dopant ions on the photoluminescence and phase formation properties of the hosts are investigated and determined as Dy3+-co-doped phoshor has the reduced excitation/emission intensities as well as decay lifetimes.

中文翻译:

Eu3 +活化的Y1.50Sc0.50O3荧光粉的光致发光特性

在这项研究中,Eu 3+活化和Dy 3+共掺杂的Y 2 O 3基荧光粉已经通过固态反应方法在露天气氛下合成。主晶格由0.25摩尔的Sc 2 O 3组成,其被添加到磷光体组合物中。因此,实施Y 3+离子的Sc 3+取代以形成Y 1.40 Sc 0.50 O 3。宿主晶格。热分析(DTA / TG)已在50°C至1400°C的温度范围内进行,以初步检查荧光粉在热处理过程中的热行为。在加热过程之后,相形成通过X射线衍射表征为Y 2 O 3单相立方结构。研究并确定了Eu 3+和Dy 3+掺杂离子对主体的光致发光和相形成特性的影响,因为Dy 3+共掺杂的磷光体具有降低的激发/发射强度以及衰变寿命。
更新日期:2020-11-02
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