Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-10-31 , DOI: 10.1016/j.cplett.2020.138133 Yan Yu , Weimin Zhu , Yu Feng , Hua Xuan , Haixiang He
In this paper, quantum wave-packet method was used to study the vibrational excitation effects for title reaction. Results of reaction probabilities, state-to-state resolved integral and differential cross sections for HD (v = 1) state were obtained. Total probabilities decrease with increasing collision energy which presents the excitation effects are not obvious in these results. However, comparing with our previous work for v = 0 state, results from integral and differential cross sections do show visible differences. The non-symmetrical profiles of differential cross sections also suggest that the life-time of complex forming is not that long for v = 1 state.
中文翻译:
D + + HD反应的振动激发效应的状态研究
本文采用量子波包方法研究了标题反应的振动激发效应。获得了反应概率,HD(v = 1)状态的状态间解析积分和微分截面的结果。总概率随碰撞能量的增加而减小,这表明在这些结果中激励效果并不明显。但是,与我们先前对v = 0状态的工作相比,积分和微分截面的结果确实显示出明显的差异。微分截面的非对称轮廓还表明,对于v = 1状态,复杂成形的寿命并不长。