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Main Group and Transition Metal-Mediated Phosphaalkene Insertion Reactions Initiated by Phosphines Containing Si–P Bond
Comments on Inorganic Chemistry ( IF 5.4 ) Pub Date : 2020-10-29 , DOI: 10.1080/02603594.2020.1837783
Mutasem Z. Bani-Fwaz 1, 2
Affiliation  

ABSTRACT

This review article focuses on 1λ3-phosphaalkene compounds derived from phosphines containing at least one silicon-phosphorous bond. 1λ3-Phosphaalkene compounds are of high value as they are used to form several phosphorous compounds containing a transition metal and main group elements. In addition to the fact that different kinds of 1λ3-phosphaalkynes are prepared from 1λ3-phosphaalkenes. Both families of phosphorous compounds; 1λ3-phosphaalkenes and 1λ3-phosphaalkynes have become important to chemists, as they are used in preparing several phosphorous compounds to be used as homogeneous catalysts in chemical reactions.



中文翻译:

含Si-P键的膦引发的主族和过渡金属介导的磷烯烃插入反应

抽象的

此综述文章集中于1λ 3由含有至少一个硅-磷键膦衍生-phosphaalkene化合物。1λ 3 -Phosphaalkene化合物是高价值的,因为它们是用于形成含过渡金属和主族元素几个磷化合物。除了不同种1λ的事实3 -phosphaalkynes从1λ制备3 -phosphaalkenes。两种磷化合物家族;1λ 3 -phosphaalkenes和1λ 3 -phosphaalkynes已成为化学家重要,因为它们是在制备用作化学反应中的均相催化剂几个磷化合物使用。

更新日期:2020-10-29
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