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Modular Tandem Mizoroki‐Heck/Reductive Heck Reactions to Construct Fluorenes from Cyclic Diaryliodoniums
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-10-29 , DOI: 10.1002/adsc.202001080
Xiaopeng Peng 1, 2 , Yang Yang 2, 3 , Bingling Luo 2 , Shijun Wen 2 , Peng Huang 2
Affiliation  

Starting from cyclic diaryliodoniums and terminal alkenes, a diverse set of fluorenes is conveniently constructed. The reactions catalyzed by palladium undergo one conventional Mizoroki‐Heck reaction and one reductive Heck reaction. The scope of alkenes is general, leading to 29 fluorenes which would expand the structural diversity of fluorene reservoir.

中文翻译:

模块化串联Mizoroki-Heck /还原性Heck反应从环状二芳基碘鎓盐构建芴

从环状二芳基碘鎓和末端烯烃开始,可以方便地构建各种芴。钯催化的反应会进行一种常规的Mizoroki-Heck反应和一种还原性Heck反应。烯烃的范围很广,导致有29个芴,这将扩大芴储层的结构多样性。
更新日期:2021-01-05
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