One‐Pot Synthesis of Spiro[fluorine‐9,9'‐xanthene] Derivatives,Chinese Journal of Chemistry

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One‐Pot Synthesis of Spiro[fluorine‐9,9'‐xanthene] Derivatives
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-10-30 , DOI: 10.1002/cjoc.202000518
Hao‐Xuan Yuan ₁ , Ying Wei ₁ , Ling‐Hai Xie ₁ , Wei Huang _{1,

2}

Affiliation

As a novel class of spirofluorenes, spirobifluorene (SBF) and spiro[fluorine‐ 9,9'‐xanthene] derivatives (SFXs) have three‐dimensional conformation, spiro‐conjugation effect, and rigid steric hindrance, which can be widely used in the fields of synthetic chemistry, materials chemistry and supramolecular chemistry. Due to their facile one‐pot synthetic route, and to the variety of molecular designs, SFXs are expected to become new spiro functional materials that replace SBF. In this review, we present the history, development and expansion of SFXs synthesis in one‐pot methods, and the advantages and limitations of one‐pot synthesis are also discussed.

中文翻译：

螺[氟-9,9'-x吨]衍生物的一锅合成

作为一类新型的螺芴，螺二芴（SBF）和螺[9,9'-FX吨]衍生物（SFX）具有三维构象，螺共轭效应和刚性位阻，可广泛用于合成化学，材料化学和超分子化学领域。由于其简便的单罐合成路线以及分子设计的多样性，SFX有望成为替代SBF的新型螺线功能材料。在这篇综述中，我们介绍了单锅法合成SFX的历史，发展和扩展，还讨论了单锅法合成的优点和局限性。

更新日期：2020-10-30

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