当前位置: X-MOL 学术J. Eur. Ceram. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
STRUCTURE OF ISOTHERMAL SECTIONS OF THE DIAGRAM OF THE STATE OF THE SYSTEM ZrO2 – La2O3 – Eu2O3 AT TEMPERATURES 1500 AND 1250 °C
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-10-21 , DOI: 10.1016/j.jeurceramsoc.2020.10.033
O.A. Kornienko , O.I. Bykov , A.V. Sameljuk , Yu.M. Bataiev

Using the methods of X-ray phase and microstructural analyzes, phase equilibria and structural transformations in the ZrO2 – La2O3 – Eu2O3 system at temperatures of 1500 and 1250 ºC in the whole range of concentrations were studied. Based on the obtained data, the corresponding isothermal cross sections are constructed. It is established that the fields of solid solutions are formed in the system on the basis of cubic (F) modification with fluorite type structure, tetragonal (T) modification ZrO2, monoclinic (B) and cubic (C) modifications Eu2O3, hexagonal (A) modification La2O3, as well as ordered phases with a structure of the pyrochlor type Ln2Zr2O7 (Py). The boundaries of the phase fields and the parameters of the unit cells of the formed phases are determined. It was found that in the region with a high content of ZrO2 solid solutions are formed on the basis of tetragonal modification of ZrO2. The solubility of La2O3 in T-ZrO2is small and is ∼ 0.5% (mol.), which is confirmed by X-ray phase analysis and microstructural studies. It is established that at 1500 and 1250°C a continuous series of solid solutions is formed on the basis of an ordered phase of pyrochlor (Py) type Ln2Zr2O7. With decreasing temperature, the region of homogeneity of the specified solid solution narrows. Isothermal cross sections of the state diagram of the ZrO2-La2O3-Eu2O3 system at 1500 and 1250°C have a similar structure, although they are characterized by some differences due to the structure of the limiting binary systems. No new phases in the ternary system ZrO2 – La2O3 – Eu2O3 were detected at the studied temperatures.



中文翻译:

在1500和1250°C的温度下ZrO 2 -La 2 O 3 -Eu 2 O 3系统状态图的等温截面的结构

使用X射线相和微观结构分析的方法,研究了ZrO 2 -La 2 O 3 -Eu 2 O 3体系在1500和1250ºC的温度下在整个浓度范围内的相平衡和结构转变。基于获得的数据,构造相应的等温截面。建立了基于萤石型结构的立方(F)改性,四方(T)改性ZrO 2,单斜晶(B)和立方(C)改性Eu 2 O 3的体系形成固溶体的场。,六角形(A)修饰La 2 O 3以及具有烧绿石型Ln 2 Zr 2 O 7(Py)结构的有序相。确定相场的边界和所形成相的单位晶胞的参数。结果发现,在该区域用的ZrO含量高2的ZrO四方修改的基础上形成的固溶体2。La 2 O 3在T-ZrO 2中的溶解度很小,约为0.5%(摩尔),这已通过X射线相分析和微观结构研究得到证实。可以确定,在1500和1250°C的条件下,根据烧绿石(Py)型Ln 2有序相形成了一系列连续的固溶体。Zr 2 O 7。随着温度降低,指定固溶体的均质区域变窄。ZrO 2 -La 2 O 3 -Eu 2 O 3系统的状态图在1500和1250°C的等温截面具有相似的结构,尽管由于有限的二元体系的结构而具有一些差异。在研究温度下,未检测到三元体系ZrO 2 -La 2 O 3 -Eu 2 O 3的新相。

更新日期:2020-12-01
down
wechat
bug