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Sulfate of potash and yellow phosphorus to simultaneously remove SO2–NO and obtain a complete fertilizer
Atmospheric Pollution Research ( IF 4.5 ) Pub Date : 2020-10-29 , DOI: 10.1016/j.apr.2020.10.017
Montaser A.M. Alzaky , Dengxin Li

Flue gas includes SOX and NOX, and is considered to be a global issue due to its severe environmental problems. Hence, scientists have recently searched for new and efficient abatement techniques. The present study aims to simultaneously remove SOX and NOX, and obtain a complete N–P–K fertilizer by applying white/yellow phosphorus (P4) and sulfate of potash (SOP). We comprehensively investigated the most efficient parameters, which were determined to be a P4 weight of 0.5 g, stirring intensity of 1778 rpm, and temperature of 55 °C. We also compared the removal efficiency with the most efficient and recently identified absorbers. Moreover, we studied the simultaneous removal efficiency, with a deeper investigation of removing NOX only. The emulsion content was investigated using inductively-coupled plasma optical-emission spectroscopy (ICP–OES), an elemental analyzer, and ion chromatography (IC). The SOP content was investigated using X-ray diffraction (XRD). The results showed that the emulsion contained all of the elements required for a complete fertilizer. Finally, the process reaction mechanism, including the intermediate elements, was thoroughly identified. Considering the wide occurrence of SOX and NOX and the need for abatement, our simple, practical, energy-saving process provides a possible means for deriving useful byproducts as oppose to discarding them.



中文翻译:

硫酸钾和黄磷的硫酸盐同时去除SO 2 -NO并获得完全肥料

烟道气包括SO X和NO X,由于其严重的环境问题,被认为是全球性问题。因此,科学家最近寻找了新的有效的减排技术。本研究旨在同时去除SO X和NO X,并通过施用白色/黄色磷(P 4)和钾盐硫酸盐(SOP)获得完整的N–P–K肥料。我们全面研究了最有效的参数,这些参数被确定为P 4重量为0.5 g,搅拌强度为1778 rpm,温度为55°C。我们还比较了去除效率与最近确定的最有效的吸收器。此外,我们研究了同时去除效率,并对仅去除NO X进行了更深入的研究。使用电感耦合等离子体发射光谱(ICP-OES),元素分析仪和离子色谱(IC)对乳液含量进行了研究。使用X射线衍射(XRD)研究SOP含量。结果表明,乳液含有完整肥料所需的所有元素。最后,彻底确定了包括中间元素在内的过程反应机理。考虑到SO X和NO X的广泛存在 由于需要减少污染物,我们简单,实用,节能的过程提供了一种有用的手段,可用来获得有用的副产品,以免被丢弃。

更新日期:2020-10-30
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