Abstract

The results of studying the dependence of the reaction rate of the hydrogen sulfide oxidation in oil with molecular oxygen in the presence of an ammonia solution of cobalt phthalocyanine on the process temperature, the consumption of the catalyst complex, and the concentration of cobalt phthalocyanine in the catalyst complex are reported. It was shown that the rate of the hydrogen sulfide oxidation strongly depends on the consumption of the catalyst complex and the concentration of cobalt phthalocyanine in the catalyst complex. Based on experimental data, a mathematical model was derived that describes the hydrogen sulfide oxidation with satisfactory accuracy. The calculated values obtained using this mathematical model are in good agreement with the experimental data.

中文翻译：

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酞菁钴氨溶液在油中用分子氧对硫化氢进行液相氧化

摘要

研究了在存在酞菁钴氨水的情况下，油中硫化氢与分子氧的氧化反应速率与工艺温度，催化剂配合物的消耗量以及钴酞菁浓度之间的关系。报告了催化剂配合物。结果表明，硫化氢的氧化速度强烈地取决于催化剂配合物的消耗和催化剂配合物中钴酞菁的浓度。根据实验数据，导出了描述满意精度的硫化氢氧化的数学模型。使用该数学模型获得的计算值与实验数据非常吻合。