Elemental sulfur (S₈) is an inexpensive chemical feedstock for polymeric materials but has the disadvantages of poor solubility in organic media and inferior physical properties in the elemental form. We report on the preparation of organosulfur chalcogenide hybrid inorganic/organic polymer (CHIPs) based on bifunctional norbornene comonomers using dynamic covalent polymerization (DCP). A poly(sulfur-random-styrene) (p(S-r-Sty)) resin was utilized to address the limited solubility/ miscibility of norbornene-containing comonomers in liquid sulfur. This report demonstrated the ability to expand the scope of organic comonomers to prepare organosulfur CHIPs from elemenatal sulfur using a combination of inverse vulcanization and dynamic covalent polymerization.

元素硫（S ₈）是一种用于聚合物材料的廉价化学原料，但是具有以下缺点：在有机介质中的溶解性差，并且元素形式的物理性能较差。我们报告使用动态共价聚合（DCP）基于双功能降冰片烯共聚单体制备有机硫硫属元素杂化无机/有机聚合物（CHIP）。甲聚（硫随机-苯乙烯）（P（S- [R -Sty））树脂用于解决含降冰片烯的共聚单体的有限的溶解度/可混溶性液体硫中。该报告证明了通过逆硫化和动态共价聚合相结合的方法，能够扩大有机共聚单体的范围，从而从elemenatal硫制备有机硫CHIP。