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Synthesis and styrene copolymerization of novel methyl and methoxy tri, tetra, penta ring-substituted isobutyl phenylcyanoacrylates
ChemRxiv Pub Date : 2020-10-23
Monique L.P. Lotto, Yasmeen Lowe, Raza Malik, Raisa A. Munshi, Udita Persaud, Saikrupa Rajaramsiva, Maximillian A. Ramirez, Claire P. Rossi, Sara M. Rocus, William S. Schjerven, Gregory Kharas

Novel methyl and methoxy tri, tetra, penta ring-substituted isobutyl phenylcyanoacrylates, RPhCH=C(CN)CO2CH2CH(CH3)2 , where R is 2,4,5-trimethyl, 2,4,6-trimethyl, 2,3,5,6-tetramethyl, pentamethyl, 2,3-dimethyl-4-methoxy, 2,5-dimethyl-4-methoxy, 2,4-dimethoxy-3-methyl, 2,4-dimethoxy-6-methyl were synthesized by the piperidine catalyzed Knoevenagel condensation of ring-substituted benzaldehydes and isobutyl cyanoacetate and characterized by CHN analysis, IR, 1H and 13C NMR. The acrylates were copolymerized with styrene in solution with radical initiation (ABCN) at 70°C. The compositions of the copolymers were calculated from nitrogen analysis.

中文翻译:

新型甲基和甲氧基三,四,五环取代的异丁基苯基氰基丙烯酸酯的合成及苯乙烯共聚

新颖的甲基和甲氧基三,四,五环取代的异丁基苯基氰基丙烯酸酯,RPhCH = C(CN)CO2CH2CH(CH3)2,其中R为2,4,5-三甲基,2,4,6-三甲基,2,3,通过以下方法合成5,6-四甲基,五甲基,2,3-二甲基-4-甲氧基,2,5-二甲基-4-甲氧基,2,4-二甲氧基-3-甲基,2,4-二甲氧基-6-甲基哌啶催化环取代的苯甲醛与氰基乙酸异丁酯的Knoevenagel缩合反应,并通过CHN分析,IR,1H和13C NMR表征。将丙烯酸酯与苯乙烯在70°C的自由基引发(ABCN)溶液中共聚。共聚物的组成由氮分析计算。
更新日期:2020-10-28
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