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Moving Electrode Impedance Spectroscopy for Accurate Conductivity Measurements of Corrosive Ionic Media
ACS Sensors ( IF 8.9 ) Pub Date : 2020-10-27 , DOI: 10.1021/acssensors.0c01465
Nikolaus Doppelhammer 1 , Nick Pellens 2 , Johan Martens 2 , Christine E A Kirschhock 2 , Bernhard Jakoby 1 , Erwin K Reichel 1
Affiliation  

A measurement cell for the use of accurate conductivity measurements of corrosive ionic media is presented. Based on the concept of moving electrode electrochemical impedance spectroscopy, exceptional measurement accuracy is achieved in a large conductivity range. Extensive testing with corrosive ionic media demonstrated the robust operation of the cell under harsh chemical conditions, up to temperatures of 130 °C. The novel design allows monitoring small conductivity changes during chemical reactions in ionic media, for instance, zeolite formation from hydrated ionic liquids.

中文翻译:

用于精确测量腐蚀性离子介质电导率的移动电极阻抗谱

介绍了一种用于精确测量腐蚀性离子介质电导率的测量单元。基于移动电极电化学阻抗谱的概念,在较大的电导率范围内实现了出色的测量精度。使用腐蚀性离子介质进行的广泛测试证明了电池在恶劣的化学条件下(高达 130 °C 的温度)的稳健运行。这种新颖的设计允许监测离子介质中化学反应过程中的微小电导率变化,例如,从水合离子液体中形成沸石。
更新日期:2020-11-25
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