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Visible‐Light‐Driven CO2 Reduction Catalyzed by a Dinuclear Nickel Complex
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-10-27 , DOI: 10.1002/ejic.202000816 Jia‐Wei Wang 1 , Jia‐Kai Sun 1 , Dong‐Cheng Liu 2 , Long Jiang 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-10-27 , DOI: 10.1002/ejic.202000816 Jia‐Wei Wang 1 , Jia‐Kai Sun 1 , Dong‐Cheng Liu 2 , Long Jiang 1
Affiliation
The utilization of synergy between two metal sites in dinuclear metal catalysts for CO2 reduction remains challenging. Herein, for the first time, we employ a dinuclear nickel complex as a molecular catalyst for visible‐light‐driven CO2 reduction with 99 % selectivity toward CO production. The photocatalytic mechanism was proposed based on the results of electrochemical measurements and fluorescent quenching experiments.
中文翻译:
双核镍配合物催化可见光驱动的二氧化碳减排
利用双核金属催化剂中的两个金属位点之间的协同作用来还原CO 2仍然具有挑战性。在这里,我们首次采用双核镍配合物作为分子催化剂,以可见光驱动的方式减少CO 2,对CO的选择性为99%。基于电化学测量结果和荧光猝灭实验,提出了光催化机理。
更新日期:2020-12-14
中文翻译:
双核镍配合物催化可见光驱动的二氧化碳减排
利用双核金属催化剂中的两个金属位点之间的协同作用来还原CO 2仍然具有挑战性。在这里,我们首次采用双核镍配合物作为分子催化剂,以可见光驱动的方式减少CO 2,对CO的选择性为99%。基于电化学测量结果和荧光猝灭实验,提出了光催化机理。