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Iron-Catalyzed Tandem Radical Addition/Cyclization: Highly Efficient Access to Methylated Quinoline-2,4-diones
Synlett ( IF 1.7 ) Pub Date : 2020-10-21 , DOI: 10.1055/s-0039-1691574
Ji-Kai Liu 1 , Huan Sun , Yue Jiang , Ming-Kun Lu , Yun-Yun Li , Li Li
Affiliation  

A visible-light-induced and iron-catalyzed oxidative radical addition/cyclization cascade reaction of N-(o-cyanoaryl)acrylamides with dimethyl sulfoxide has been developed. The method exhibits a wide substrate scope and an excellent functional-group tolerance, thus providing an efficient and convenient access to a variety of methylated quinoline-2,4-diones.

中文翻译:

铁催化串联自由基加成/环化:高效获得甲基化喹啉-2,4-二酮

已开发出 N-(邻氰基芳基)丙烯酰胺与二甲基亚砜的可见光诱导和铁催化氧化自由基加成/环化级联反应。该方法具有广泛的底物范围和优异的官能团耐受性,从而为获取各种甲基化喹啉-2,4-二酮提供了高效便捷的途径。
更新日期:2020-10-21
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