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Zinc imidazolate framework-8 nanoparticle application in oil removal from oil/water emulsion and reuse
Journal of Nanoparticle Research ( IF 2.5 ) Pub Date : 2020-10-26 , DOI: 10.1007/s11051-020-05036-w
Meiry Gláucia Freire Rodrigues , Tellys Lins Almeida Barbosa , Diogo Pierre Alves Rodrigues

Water pollution is one of the biggest problems in the world and treatment is very important. ZIF-8 is a promising nanomaterial for water treatment. In this study, zinc imidazolate framework-8 (ZIF-8) nanoparticles were prepared via a solvothermal method. The synthesized were characterized by using several techniques and applied in emulsified oil/water separation and reuse. A combination of techniques (XRD, BET, SEM) showed that the crystalline phase of the ZIF-8 was successfully obtained by the solvothermal method. ZIF-8 exhibits a high surface area of 1146 m2/g and an average nanoparticle size 47 ± 4.6 nm. ZIF-8 exhibits a very high adsorption capacity reached 2811.1 mg/g and it was regenerated by the ethanol-washing method. The process of regeneration of ZIF-8 has proved to be efficient. ZIF-8 was regenerated by a simple ethanol-washing method; the regenerated ZIF-8 exhibited more than 98% of regeneration efficiency over three cycles.



中文翻译:

咪唑锌盐骨架8纳米颗粒在油/水乳状液除油和再利用中的应用

水污染是世界上最大的问题之一,处理非常重要。ZIF-8是一种有前途的水处理纳米材料。在这项研究中,通过溶剂热法制备了咪唑锌锌骨架8(ZIF-8)纳米粒子。利用几种技术对合成物进行了表征,并应用于乳化油/水的分离和再利用。结合多种技术(XRD,BET,SEM)表明,通过溶剂热法成功获得了ZIF-8的晶相。ZIF-8的高表面积为1146 m 2/ g,平均纳米颗粒尺寸为47±4.6 nm。ZIF-8表现出非常高的吸附容量,达到2811.1 mg / g,并通过乙醇洗涤方法再生。ZIF-8的再生过程已证明是有效的。ZIF-8通过简单的乙醇洗涤方法再生;再生的ZIF-8在三个循环中显示出超过98%的再生效率。

更新日期:2020-10-27
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