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Sustainable N-doped hierarchical porous carbons as efficient CO2 adsorbents and high-performance supercapacitor electrodes
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2020-10-20 , DOI: 10.1016/j.jcou.2020.101326
Ghazanfar Nazir , Adeela Rehman , Soo-Jin Park

Herein, a series of ACs are prepared with and without nitrogen doping at two different activation temperatures i.e., 800 °C and 900 °C. As-prepared ACs possess a high surface area (1142 - 2211 m2 g−1), large total pore volume (0.641 - 2.018 cm3 g−1), and a well-developed porous structure. At 1 bar, ACs demonstrate a remarkable CO2 uptake of 2.86 - 6.90 mmol g−1 at 273 K and 2.22 - 4.71 mmol g−1 at 298 K. This is attributed to the large ultra-micropore volume of pore size (< 0.73 nm), a prerequisite for achieving high CO2 adsorption. Finally, ACs based electrodes used for supercapacitors display high specific capacitance (100 - 204 Fg−1 at 0.5 Ag−1), and outstanding stability (∼ 92 % capacity retained even after 1000 cycles). It is shown that glucose-derived carbon precursor activated by potassium hydroxide at 900 °C denoted as “CK-900” proves to be the best sample for CO2 adsorption due to its narrow pore size, whereas glucose derived carbon precursor with melamine (acts as a nitrogen doping material) activated by potassium hydroxide at 900 °C denoted as “CNK-900” exhibits the best supercapacitive characteristics owing to its wider pore size distribution, high pore volume, and optimum nitrogen content. The remarkable CO2 uptake and energy storage capacities are attributed to high surface area, optimum nitrogen doping, and micro-mesopores volume of ACs framework.



中文翻译:

可持续的N掺杂分级多孔碳,作为有效的CO 2吸附剂和高性能超级电容器电极

在此,在两个不同的激活温度(即800°C和900°C)下,制备了带有和不带有氮掺杂的一系列AC。所制备的AC具有高的表面积(1142至2211m 2 g -1),大的总孔体积(0.641至2.018cm 3 g -1)以及发达的多孔结构。在1 bar下,ACs在273 K时显示出2.86-6.90 mmol g -1的惊人CO 2吸收,在298 K时显示2.22-4.71 mmol g -1的显着吸收。这归因于孔径超大的超微孔体积(<0.73 nm),这是实现高CO 2的前提吸附。最后,用于超级电容器AC的基于电极显示出高的比电容(100 - 204蛋白原-1 0.5银-1),和显着的稳定性(〜92%的容量保持甚至1000次循环后)。结果表明,氢氧化钾在900°C下活化的葡萄糖衍生碳前体称为“ CK-900”,由于其孔径狭窄而被证明是最佳的CO 2吸附样品,而葡萄糖衍生的碳前体与三聚氰胺(作用作为一种氮掺杂材料)在900°C时被氢氧化钾活化,表示为“ CNK-900”,因为它具有较宽的孔径分布,较高的孔体积和最佳的氮含量,因此具有最佳的超电容特性。卓越的CO 2 吸收和能量存储能力归因于AC框架的高表面积,最佳氮掺杂和微中孔体积。

更新日期:2020-10-30
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