A New Mechanically‐Interlocked [Pd2L4] Cage Motif by Dimerization of two Peptide‐based Lemniscates,Angewandte Chemie International Edition

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A New Mechanically‐Interlocked [Pd2L4] Cage Motif by Dimerization of two Peptide‐based Lemniscates
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-10-19 , DOI: 10.1002/anie.202013825
Thorben R. Schulte ₁ , Julian J. Holstein ₁ , Laura Schneider ₁ , Abdulselam Adam ₂ , Gebhard Haberhauer ₂ , Guido H. Clever ₁

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Dinuclear cages are metallo‐supramolecular hosts assembled from a minimum of components. Numerous examples for the most trivial, lantern‐shaped topology (two metals bridged by three or four bowed ligands) have been reported, but other structural motifs are rare. In their Communication (DOI: 10.1002/anie.202010995), G. H. Clever et al. detail a new variety for a [Pd₂Ligand₄] assembly, consisting of two figure‐eight‐shaped chelate complexes, doubly connected by mechanical bonds. The chiral ligands are based on peptidic macrocycles, giving the nano‐sized object a natural product‐like character.

中文翻译：

一种新的机械连锁的[Pd2L4]笼式母题，通过两个基于肽的裙带菜的二聚化

双核笼是由最少的组件组装而成的金属超分子宿主。已经报道了许多最简单的灯笼形拓扑结构的例子（两种金属被三个或四个弓形配体桥接），但是很少有其他结构性图案。G. H. Clever等人在其通讯（DOI：10.1002 / anie.202010995）中详细介绍了[Pd ₂配体₄ ]装配的新品种，该品种由两个通过机械键双重连接的八字形螯合物组成。手性配体基于肽大环，使纳米尺寸的物体具有天然的类产品特征。

更新日期：2020-10-19

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